Fermer

Bruno Therrien


 

Associate Professor (Canada)

e-mail: bruno.therrien@unine.ch




 

Research Interests / Projects


200021-
113282

Supramolecular Assemblies from Ruthenium Complexes (SNF 200020 -129518)

 

 

 

 

 

Introduction of transition metal in the self-assembly of discrete supramolecular structures has recently received a great attention. Both, two- and three-dimensional structures, are found in the literature and the interest in these complex systems lie in the scientific field of chemistry (recognition and selective transformations), biology (translocation of drugs across membranes, biomimetics), and material science (construction of macroscopic architectures and devices at the molecular level). Their synthesis involves a directional-bonding approach in which the metal centres, the multibranched ligands, or a combination of both, control the geometric shapes or polyhedra of the resulting assemblies. When systems containing ruthenium atoms in a two-dimensional fashion are relatively common, three-dimensional structures incorporating ruthenium atoms are scarce. This project originates from the introduction of arene ruthenium building blocks in the self-assembly with 2,4,6-tri(pyridyl)-1,3,5-triazine subunits of hexanuclear metalloprisms. The synthesis of these new metalla-prismatic compounds have opened a wide perspective for bio- and nano-applications and therefore this research project intends to exploit the potential of arene ruthenium moieties in self-assemblies in order to design nano-structured molecules such as supramolecular squares and rectangles, chiral triangular prisms and supramolecular host-guest systems.

   

200021-
111795

Functionalised Arene-Ruthenium Complexes: Bridging the Gap from Bio- to Nano-Materials

 

01.04.2006

31.03.2008

 

 

 
This interdisciplinary research project is based around the development of arene-ruthenium complexes. So far, the research on arene-ruthenium complexes has been mainly concentrated around ligands directly attached to the ruthenium atom, the arene moiety playing only a minor role. Therefore, introducing functionalised moieties to the coordinated arene ligand opens the door to the generation of new compounds which can be used for various applications. The project is intended to exploit the potential of functionalised arene-ruthenium complexes in mainly two fields: As biological active compounds and as building block in the construction of nano-materials. The bio-inorganic part will focus on the synthesis of specific targeted complexes which incorporate bio-active unit. These mono-functionalised arene-ruthenium complexes possessing a bio-sensor will find application primarily as anticancer and antiviral agents. The synthetic work will be carried out in Neuchâtel and the biological activity will be performed in collaboration with the laboratory of Prof. Dyson in Lausanne . The nano-materials part implies the synthesis of multi-functionalised arene-ruthenium building blocks which will be used in the preparation of more elaborated architectures such as polymers, dendrimers, squares, grids or capsules.

Education

2004 Tokyo University , Japan , Postdoctoral position in Inorganic Chemistry under the direction of Prof. Makoto Fujita.

 

2003 Chiba University , Japan , Postdoctoral position in Inorganic Chemistry under the direction of Prof. Kentaro Yamaguchi.

 

2002 Neuchâtel University , Switzerland , Postdoctoral position in Inorganic Chemistry under the direction of Prof. Georg Süss-Fink.

 

2001 Massey University , New Zealand , Postdoctoral position in Inorganic Chemistry under the direction of Prof. Anthony K. Burrell.

 

1999 Weizmann Institute, Israel, Postdoctoral position in Protein Crystallography under the direction of Prof. Zippora Shakked.

 

1998 University of Berne , Switzerland , PhD in Chemistry under the direction of Dr. Thomas R. Ward.

 

1993 University of Montréal , Canada ,Masters Degree in Chemistry under the direction of Prof. André L. Beauchamp.

 

1989 University of Montréal, Canada, Baccalauréat ès science.

Responsabilities

1995 -1998 Demonstrator for practical coordination chemistry at the

University of Berne


1993-1994 Lecturer in inorganic chemistry parts I and II, and in charge of the corresponding practical laboratory at the

University of Trois-Rivières


1993-1994 Teacher in inorganic chemistry at Collège Lionel-Groulx


1991-1992 Demonstrator for practical crystallography at the

University of Montreal


1990-1991 Demonstrator for practical inorganic chemistry at the

University of Montreal

Additional Skills

Proficient with PC's, Mac's and Unix, and many software packages including Word, CSC chemdraw, Canvas, Win-nmr and others

 

X-rays structure measurements on a R-AXIS IIC (Rigaku), a CCD (Siemens) or a CAD4 (Enraf Nonius) and solution/refinement with SHELX or NRCVAX.

 

Glove-box and Schlenck techniques.

 

Utilization of different methods for the characterization of organic compounds: NMR, HPLC, GC, IR, Circular dichroism and mass spectroscopy.

 

Bilingual: French and English. Good reading and reasonable aural understanding in German.

Publications

201-System biology approach for in vivo photodynamic therapy optimization of ruthenium-porphyrin compounds
M. Pernot, T. Bastogne, N. P. E. Barry, B. Therrien, G. Koellensperger, S. Hann, V. Reshetov, M. Barberi-Heyob, J. Photochem. Photobiol. B: Biology, doi: 10.1016/j.jphotobiol.2012.08.012.

200-Interaction of a ruthenium hexacationic prism with amino acids and biological ligands: ESI mass spectrometry and NMR characterization of the reaction products
L. Paul, B. Therrien, J. Furrer, J. Biol. Inorg. Chem., 2012, 17, 1053-1062.

199-Photoactive sawhorse-type diruthenium tetracarbonyl complexes
J. P. Johnpeter, F. Schmitt, E. Denoyelle-Di-Muro, G. Wagnières, L. Juillerat-Jeanneret, B. Therrien, Inorg. Chim. Acta, doi: 10.1016/j.ica.2012.05.026.

198-Ruthenium(II) complexes bearing a ligand derived from P,N- or P,N,O- diphenylphosphino-benzoxazine: Synthesis, X-ray characterization, and cis diastereoselectivity in styrene cyclopropanation
G. A. Ardizzoia, S. Brenna, S. Durini, B. Therrien, Organometallics, 2012, 31, 5427-5437.

197-Sawhorse-type diruthenium tetracarbonyl tweezers
J. P. Johnpeter, J. Mohanraj, N. Armaroli, B. Therrien, Eur, J. Inorg. Chem., 2012, 3449-3455.

196-Highly cytotoxic trithiophenolatodiruthenium complexes of the type [(η6-p-MeC6H4Pri)2Ru2(SC6H4-p-X)]+: Synthesis, molecular structure, electrochemistry, cytotoxicity and glutathione oxidation potential
F. Giannini, J. Furrer, A.-F. Ibao, G. Süss-Fink, B. Therrien, O. Zava, M. Baquie, P. J. Dyson, P. Štěpnička, J. Biol. Inorg. Chem., 2012, 17, 951-960.

195-Enhancement of cytotoxicity by combining pyrenyl-dendrimers and arene ruthenium metalla-cages
A. Pitto-Barry, O. Zava, P. J. Dyson, R. Deschenaux, B. Therrien, Inorg. Chem., 2012, 51, 7119-7124.

194-Syntheses and structural studies of mononuclear arene ruthenium complexes with nitrogen-based chelating ligands
G. Gupta, B. Therrien, S. Park, S. S. Lee, J. Kim, J. Coord. Chem., 2012, 65, 2523-2534.

193-Heterodinuclear arene ruthenium complexes containing a glycine-derived phosphinoferrocene carboxamide: Synthesis, molecular structure, electrochemistry, and catalytic oxidation activity in aqueous media
J. Tauchman, B. Therrien, G. Süss-Fink, P. Štěpnička, Organometallics, 2012, 31, 3985-3994.

192-Bio-metallodendrimers - Emerging therapeutics in metal-based drug design
P. Govender, B. Therrien, G. S. Smith, Eur. J. Inorg. Chem., 2012, 2853-2862.

191-Cellular delivery of pyrenyl-arene ruthenium complexes by a water-soluble arene ruthenium metalla-cage
M. A. Furrer, F. Schmitt, M. Wiederkehr, L. Juillerat-Jeanneret, B. Therrien, Dalton Trans., 2012, 41, 7201-7211.

190-Heteronuclear complexes containing the N,N'-di(2-pyridyl)amidocarboxylferrocene ligand
M. Auzias, B. Therrien, G. Süss-Fink, Inorg. Chim. Acta, 2012, 387, 446-449.

189-Physical and physico-chemical stimuli-responsive arene ruthenium metalla-prism
M. A. Furrer, J. Furrer, B. Therrien, Organometallics, 2012, 31, 3149-3154.

188-Investigation of the reactivity between a ruthenium hexacationic prism and biological ligands
L. Paul, B. Therrien, J. Furrer, Inorg. Chem., 2012, 51, 1057-1067.

187-Encapsulation of hydrophobic pyrenyl-cycloplatinate complexes within a water-soluble arene ruthenium metalla-cage
N. P. E. Barry, O. Zava, W. Wu, J. Zhao, B. Therrien, Inorg. Chem. Commun., 2012, 18, 25-28.

186-Encapsulation of inorganic and organic guest molecules into an organometallic hexacationic arene osmium metalla-prism: Synthesis, characterisation and anticancer activity
N. P. E. Barry, O. Zava, P. J. Dyson, B. Therrien, J. Organomet. Chem., 2012, 705, 1-6.

185-Delivery of floxuridine derivatives to cancer cells by water-soluble organometallic-cages
J. Wu Yi, N. P. E. Barry, M. A. Furrer, O. Zava, P. J. Dyson, B. Therrien, B. H. Kim, Bioconjugate Chem., 2012, 23, 461-471.

184-Thiolato-bridged arene ruthenium complexes: Synthesis, molecular structure, reactivity and anticancer activity of the dinuclear complexes (arene)2Ru2(SR)2Cl2
A.-F. Ibao, M. Gras, B. Therrien, G. Süss-Fink, O. Zava, P. J. Dyson, Eur. J. Inorg. Chem., 2012, 1531-1535.

183-Organometallic cages as vehicles for intracellular release of photosensitizers
F. Schmitt, J. Freudenreich, N.P.E. Barry, L. Juillerat-Jeanneret, G. Süss-Fink, B. Therrien, J. Am. Chem. Soc., 2012, 134, 754-757.

 182-Drug delivery by water-soluble organometallic cages, B. Therrien, Top. Curr. Chem., 2011, doi: 10.1007/128_2011_272.

181-Efficient photodynamic therapy of cancer using chemotherapeutic porphyrin-ruthenium arene metalla-cubes, F. Schmitt, N. P. E. Barry, L. Juillerat-Jeanneret, B. Therrien, Biol. Med. Chem. Lett., 2011, doi: 10.1016/j.bmcl.2011.11.058.

180-Organotin(IV) trifluoromethanesulfonates chemistry: Isolation and characterization of a new di-n-butyl derivative presenting a Sn3O3 core, L. Plasseraud, B. Therrien, A. Růžička, H. Cattey, Inorg. Chim. Acta, 2011, doi: 10.1016/j.ica.2011.08.042.

179-Ni(II) and Pd(II) pyridinyloxazolidine-compounds: Synthesis, X-ray characterisation and catalytic activities in the aza-Michael reaction, G. A. Ardizzoia, S. Brenna, B. Therrien, Dalton Trans., 2011, doi: 10.1039/C1DT11191D.

178-{6-Hydroxymethyl)pyridin-2-yl}methyl ferrocene-1-carboxylate, M. Auzias, G. Süss-Fink, B. Therrien, Acta Cryst., 2011, E67, m1618.

177-Dichlorido[1-(2-chloroethyl)-3-(pyridin-4-ylmethyl-κN)urea](η6-hexamethyl-benzene)ruthenium(II) chloroform monosolvate, M. Auzias, G. Süss-Fink, B. Therrien, Acta Cryst., 2011, E67, m1613.

176-Dichlorido(furfurylamine-κN)(η6-hexamethylbenzene)ruthenium(II), A. Garci, T.-T. Thai, G. Süss-Fink, B. Therrien, Acta Cryst., 2011, E67, m1592.

 175-Targeted and multifunctional arene ruthenium chemotherapeutics, G. S. Smith, B. Therrien, Dalton Trans., 2011, 40, 10793-10800.

174-Reactivity study of arene(azido)ruthenium N∩O-base complexes with activated alkynes, S. L. Nongbri, B. Therrien, K. Mohan Rao, Inorg. Chim. Acta, 2011, 376, 428-436.

173-Arene ruthenium bis-saccharinato complexes: Synthesis, molecular structure and catalytic oxidation properties in aqueous solution, T.-T. Thai, B. Therrien, G. Süss-Fink, J. Organomet. Chem., 2011, 696, 3285-3291.

172-Anticancer activity of tetra-cationic arene ruthenium metalla-cycles, N. P. E. Barry, F. Edafe, B. Therrien, Dalton Trans., 2011, 40, 7172-7180.

171-Encapsulation of pyrene functionalised poly(benzyl ether) dendrons into an arene ruthenium metalla-cage, A. Pitto-Barry, N. P. E. Barry, O. Zava, R. Deschenaux, B. Therrien, Chem. Asian J., 2011, 6, 1595-1603.

170-Ru2(CO)4(OOCR)2L2 sawhorse-type complexes containing axial 5¬(4-pyridyl)-10,15,20-triphenylporphyrin ligands, M. Gras, N. P. E. Barry, B. Therrien, G. Süss-Fink, Inorg. Chim. Acta, 2011, 371, 59-62.

169-Mono- and dinuclear (η6-arene) ruthenium(II) benzaldehyde thiosemicarbazone complexes: Synthesis, characterization and cytotoxicity, T. Stringer, B. Therrien, D. T. Hendricks, H. Guzgay, G. S. Smith, Inorg. Chem. Commun. 2011, 14, 956-960.

168-Excellent correlation between drug release and portal size in metalla-cages drug delivery systems, N. P. E. Barry, O. Zava, P. J. Dyson, B. Therrien, Chem. Eur. J., 2011, 17, 9669-9677.

167-[Bis(2-pyridyl-κN)amine]chlorido(η6-hexamethylbenzene)ruthenium(II) hexafluoridophosphate dichloromethane solvate, G. Gupta, B. Therrien, J. Kim, Acta Cryst. 2011, E67, m548.

166-Template-directed synthesis of hexanuclear arene ruthenium complexes with trigonal-prismatic architecture based on 2,4,6-tris(3-pyridyl)triazine ligands, J. Freudenreich, J. Furrer, G. Süss-Fink, B. Therrien, Organometallics, 2011, 30, 942-951.

165-Ru2(CO)4{OOC(CH2)nCH3}2L2 sawhorse-type complexes containing μ2-η2-carboxylato ligands derived from saturated fatty acids, J. Johnpeter, B. Therrien, J. Struct. Chem., 2011, 52, 151-159.

164-Study of complexes of platinum group metals containing nitrogen bases derived from pyridine aldehydes: Interesting molecular structures with unpredicted bonding modes of the ligands, G. Gupta, S. Gloria, S. L. Nongbri, B. Therrien, K. Mohan Rao, J. Organomet. Chem., 2011, 696, 2014-2022.

163-Study of half sandwich platinum group metal complexes containing tetradentate N-donor ligand bearing two di-pyridylamine units linked by an aromatic spacer, G. Gupta, S. Gloria, B. Therrien, B. Das, K. Mohan Rao, J. Organomet. Chem., 2011, 696, 702-708.

162-Antiproliferative activity of chelating N,O- and N,N-ruthenium(II) arene functionalised poly(propyleneimine) dendrimer scaffolds, P. Govender, A. K. Renfrew, C. M. Clavel, P. J. Dyson, B. Therrien, G. S. Smith, Dalton Trans. 2011, 40, 1158-1167.

161-Coordination chemistry of 2,4,6-tri(pyridyl)-1,3,5-triazine ligands, B. Therrien, J. Organomet. Chem., 2011, 696, 637-651.

160-Double targeting of tumours with pyrenyl-modified dendrimers encapsulated in an arene-ruthenium metalla-prism, A. Pitto-Barry, N. P. E. Barry, O. Zava, R. Deschenaux, P. J. Dyson, B. Therrien, Chem. Eur. J., 2011, 17, 1966-1971.

159-Synthesis, characterisation and anticancer activity of porphyrin containing organometallic cubes, N.P.E. Barry, O. Zava, P.J. Dyson, B. Therrien, Aust. J. Chem., 2010, 63, 1529-1537.

158-Thiophenolato-bridged dinuclear arene ruthenium complexes: A new family of highly cytotoxic anticancer agents, M. Gras, B. Therrien, G. Süss-Fink, O. Zava, P.J. Dyson, Dalton Trans., 2010, 39, 10305-10313.

157-Drug delivery of lipophilic pyrenyl derivatives by encapsulation in a water soluble metalla-cage, J. Mattsson, O. Zava, A.K. Renfrew, P.J. Dyson, S. Sei, K. Yamaguchi, B. Therrien, Dalton Trans., 2010, 39, 8248-8255.

156-In- and out-of-cavity interactions by modulating the size of ruthenium metallarectangles, N.P.E. Barry, J. Furrer, B. Therrien, Helv. Chim. Acta, 2010, 93, 1313-1328.

155-The adaptable coordination chemistry of 6-chloro-2-(quinolin-2-yl)-2,4-dihydro-1H-benzo[d][1,3]oxazine towards zinc(II) and mercury(II), G. A. Ardizzoia, S. Brenna, B. Therrien, Eur. J. Inorg. Chem., 2010, 3365-3371.

154-Anticancer activity of opened arene ruthenium metalla-assemblies, N.P.E. Barry, O. Zava, J. Furrer, P.J. Dyson, B. Therrien, Dalton Trans., 2010, 39, 5272-5277.

153-Encapsulation and host-guest properties of aromatic molecules in hexanuclear arene ruthenium prismatic cages, J. Freudenreich, N. P. E. Barry, G. Süss-Fink, B. Therrien, Eur. J. Inorg. Chem., 2010, 2400-2405.

152-Synthesis and characterization of mono and dinuclear complexes of platinum group metals bearing benzene-linked bis(pyrazolyl)methane ligands, K.T. Prasad, B. Therrien, K. Mohan Rao, J. Organomet. Chem., 2010, 695, 1375-1382.

151-Anticancer activity of new organo-ruthenium, rhodium and iridium complexes containing the 2-(pyridine-2-yl)thiazole N,N-chelating ligand, M. Gras, B. Therrien, G. Süss-Fink, A. Casini, F. Edafe, P.J. Dyson, J. Organomet. Chem., 2010, 695, 1119-1125.

150-Half-sandwich platinum group metal complexes containing tetradentate N-donor ligand bearing two pyrazolyl-pyridine units linked by an aromatic spacer, G. Gupta, B. Therrien, K. Mohan Rao, J. Organomet. Chem., 2010,695, 753-759.

149-Mono and dinuclear half-sandwich platinum group metal complexes bearing pyrazolyl-pyrimidine ligands: Syntheses and structural studies, K.T. Prasad, B. Therrien, S. Geib, K. Mohan Rao, J. Organomet. Chem., 2010, 695, 495-504.

148-Anticancer activity of osmium metalla-rectanglesN. P. E. Barry, F. Edafe, P. J. Dyson, B. Therrien, Dalton Trans. 2010, 39, 2816-2820.

147-Modulating the host-guest properties of tetranuclear arene ruthenium metalla-rectangles to accommodate a pyrene molecule , N. P. E. Barry, J. Furrer, J. Freudenreich, G. Süss-Fink, B. Therrien, Eur. J. Inorg. Chem., 2010, 725-728.

146-Evidence for drug release from a metalla-cage delivery vector following cellular internalisation, O. Zava, J. Mattsson, B. Therrien, P. J. Dyson, Chem., Eur. J., 2010, 16, 1428-1431.

145-Bimetallic ruthenium-tin chemistry: Synthesis and molecular structure of arene ruthenium complexes containing trichlorostannyl ligands, B. Therrien, T.-T. Thai, J. Freudenreich, G. Süss-Fink, S.S. Shapovalov, A.A. Pasynskii, L. Plasseraud, J. Organomet. Chem., 2010, 695, 409-414.

144-Mono and dinuclear complexes of half-sandwich platinum group metals (Ru, Rh and Ir) bearing a flexible pyridyl-thiazole multidentate donor ligand, K.T. Prasad, B. Therrien, K. Mohan Rao, J. Organomet. Chem., 2010, 695, 226-234.

143-Interactions of ruthenium coordination cubes with DNA, N.P.E. Barry, N.H. Abd Karim, R. Vilar, B. Therrien, Dalton Trans., 2009, 10717-10719.

142-Arene ruthenium oxinato complexes: Synthesis, molecular structure and catalytic activity for the hydrogenation of carbon dioxide in aqueous solution, T.-T. Thai, B. Therrien, G. Süss-Fink, J. Organomet. Chem., 2009, 694, 3973-3981.

141-6-p-Cymene){bis(trichloridostannyl-κSn)}(triethylphosphite-κP)ruthenium(II), S.S. Shapovalov, B. Therrien, Acta Cryst. 2009, E65, m1418.

140-Host-guest chemistry in the hexanuclear arene ruthenium metalla-prismatic cage [Ru6(p-cymene)6(tpt)2(dhnq)3] 6+, N.P.E. Barry, B. Therrien, Eur. J. Inorg. Chem., 2009, 4695-4700.

139-Synthesis and structural characterisation of binuclear palladium(II) complexes of salicylaldehyde dithiosemicarbazones, T. Stringer, P. Chellan, B. Therrien, N. Shunmoogam-Gounden, D.T. Hendricks, G.S. Smith, Polyhedron, 2009, 28, 2839-2846.

138-Sawhorse-type diruthenium tetracarbonyl complexes, B. Therrien, G. Süss-Fink, Coord. Chem. Rev., 2009, 253, 2639-2664.

137-Highly efficient NMR enantiodiscrimination of chiral octanuclear metalla-boxes in polar solvent, N.P.E. Barry, M. Austeri, J. Lacour, B. Therrien, Organometallics, 2009, 28, 4894-4897.

136-Anticancer activity of multinuclear arene ruthenium complexes on dendritic polypyridyl scaffolds, P. Govender, N. C. Antonels, J. Mattsson, A. K. Renfrew, P. J. Dyson, J. R. Moss, B. Therrien, G. S. Smith, J. Organomet. Chem., 2009, 694, 3470-3476.

135-Pentamethylcyclopentadienyl rhodium and iridium complexes containing oxinato ligands, T.-T. Thai, B. Therrien, G. Süss-Fink, Inorg. Chem. Commun., 2009, 12, 806-807.

134-Rhodium(I) iminophosphine poly(propyleneimine) dendrimers: Synthesis, characterization and molecular structure of a mononuclear analogue, N. C. Antonels, B. Therrien, J. R. Moss, G. S. Smith, Inorg. Chem. Commun., 2009, 12, 716-719.

133-Synthesis, molecular structure and anticancer activity of cationic arene ruthenium metalla-rectangles, J. Mattsson, P. Govindaswamy, A. K. Renfrew, P. J. Dyson, P. těpnička, G. Süss-Fink, B. Therrien, Organometallics, 2009, 28, 4350-4357.

132-Arene ruthenium cages: Boxes full of surprises, B. Therrien, Eur. J. Inorg. Chem., 2009, 2445-2453.

131-Photochemical [2 + 2] cycloaddition of the olefinic double bonds in the supramolecular rectangle [Ru4(p-cymene)4(oxalato)2(4,4'-bipyridylethylene)2] 4+, N. P. E. Barry, B. Therrien, Inorg. Chem. Commun., 2009, 12, 465-468.

130-Study of novel η5-cyclopentadienyl and η6-arene platinum group metal complexes containing a N4-type ligand and their structural characterization, G. Gupta, G. P. A. Yap, B. Therrien, K. Mohan Rao, Polyhedron, 2009, 28, 844-850.

129-Sawhorse-type diruthenium tetracarbonyl complexes containing porphyrin-derived ligands as highly selective photosensitizers for female reproductive cancer cells, F. Schmitt, M. Auzias, P. těpnička, S. Sei, K. Yamaguchi, G. Süss-Fink, B. Therrien, L. Juillerat-Jeanneret, J. Biol. Inorg. Chem., 2009, 14, 693-701.

128-New dinuclear Ru2(CO)4 sawhorse-type complexes containing bridging carboxylato ligands, M. Auzias, J. Mattsson, B. Therrien, G. Süss-Fink, Z. Anorg. Allg. Chem., 2009, 653, 115-119.

127-Combined arene ruthenium porphyrins as chemotherapeutics and photosensitizers for cancer therapy, F. Schmitt, P. Govindaswamy, O. Zava, G. Süss-Fink, L. Juillerat-Jeanneret, B. Therrien, J. Biol. Inorg. Chem., 2009, 14, 101-109.

126-Arene ruthenium complexes with ferrocene ¬derived ligands: Synthesis and molecular structure of [Ru(η 6 -arene)Cl 2 (L)] and [Ru(η 6 ¬arene)Cl2(NC3H3N(CH2)2O2C¬C5H4FeC5H5)], M. Auzias, J. Gueniat, B. Therrien, G. Süss-Fink, A. K. Renfrew, P. J. Dyson, J. Organomet. Chem., 2009, 694, 855-861.

125-Functionalised h 6 -arene ruthenium complexes, B. Therrien , Coord. Chem. Rev. 2009, 253, 493-519.

124-Water-soluble arene ruthenium complexes containing pyridinethiolato ligands:  Synthesis, molecular structure, redox properties and anticancer activity of the cations [(η6-arene)Ru(p-SC5H4NH)3] 2+, M. Gras, B. Therrien, G. Süss-Fink, P. těpnička, A. K. Renfrew, P. J. Dyson, J. Organomet. Chem., 2008, 693, 3419-3424.

123- Organometallic boxes built from 5,10,15,20­tetra(4­pyridyl)porphyrin panels and hydroxyquinonato-bridged diruthenium clips , N. P. E. Barry, P. Govindaswamy, J. Furrer, G. Süss-Fink, B. Therrien , Inorg. Chem. Commun., 2008, 11, 1300-1303.

122-Cationic half-sandwich complexes (Rh, Ir, Ru) containing 2-substituted-1,8-naphthyridine chelating ligands: Syntheses, X-ray structure analyses and spectroscopic studies, K. T. Prasad, B. Therrien, K. M. Rao, J. Organomet. Chem., 2008, 693, 3049-3056.

121- Encapsulation of aromatic molecules in hexanuclear arene ruthenium cages: A strategy to build up organometallic carceplex prisms with a dangling arm standing out /// , J. Mattsson, P. Govindaswamy, J. Furrer, S. Sei, K. Yamaguchi, G. Süss-Fink, B. Therrien , Organometallics, 2008, 27, 4346-4356.

120-Inducing helical chirality by deforming hexanuclear metalloprismatic structures, B. Therrien , G. Süss-Fink, Chimia, 2008, 62, 514-518.

119- Encapsulation of triphenylene derivatives in the self-assembled hexanuclear arene ruthenium metallo-prismatic cage [Ru6(p-PriC6H4Me)6(tpt)2(C6H2O4)3] 6+   P. Govindaswamy, J. Furrer, G. Süss-Fink, B. Therrien , Z. Anorg. Allg. Chem. 2008, 634, 1349-1352.

118-The "complex-in-a-complex" cations [(acac)2MÌRu6(p-PrC6­H4­Me)6(tpt)2(dhbq)3] 6+ (M = Pd, Pt): a Trojan Horse for cancer cells, B. Therrien , G. Süss-Fink,  P. Govindaswamy, A. K. Renfrew, P. J. Dyson, Angew. Chem. Int. Ed. 2008, 47, 3773-3776.

117-Mononuclear arene ruthenium complexes containing 5,6­diphenyl-3-(pyridine-2-yl)-1,2,4-triazine as chelating ligand: Synthesis and molecular structure, B. Therrien , C. Saïd-Mohamed , G. Süss-Fink, Inorg. Chim. Acta 2008, 361, 2601-2608.

116-Synthesis of benzene ruthenium triazolato complexes by [3+2] cycloaddition reaction of activated alkynes and fumaronitrile to benzene ruthenium azido complexes, K. Pachhunga, B. Therrien, K. Mohan Rao, Inorg. Chim. Acta, 2008, 361, 3294-3300.

115-Ruthenium-porphyrin compounds for photodynamic cancer therapy , F. Schmitt, P. Govindaswamy, G. Süss-Fink, W. H. Ang, P. J. Dyson, L. Juillerat-Jeanneret, B. Therrien , J. Med. Chem. 2008 , 51, 1811-1816.

114- High resolution STM images and molecular modelling of the absorption of 2,4,6-tri(2'-thienyl)-1,3,5-trizaine on Si-B interface at room temperature , F. Chérioux, F. Palmino, E. Duverger,  Y. Makoudi,  M. Arab,   B. Therrien, M. J.-L. Tschan, G. Süss-Fink, C. Ramseyer, Phys. Rev. Lett. 2008, 100 , 076405.

113-Ferrocenyl pyridine arene ruthenium complexes as anti-tumour agents: Synthesis, molecular structure, electrochemistry and cytotoxic properties , M. Auzias, B. Therrien , G. Süss-Fink, P. těpnička, W. H. Ang, P. J. Dyson, Inorg. Chem. 2008, 578-583.

112- Electron-structure calculations and bond order analysis using density function theory of cationic dinuclear arene ruthenium complexes , E. Penka Fowe, B. Therrien, G. Süss-Fink, C. Daul, Inorg. Chem., 2008, 47 , 42-48 .

111- Self-assembled chloro-bridged metallo-prismatic cations of the general formula [M6(η5-C5Me5)63-tpt)2(μ-Cl)6] 6+ (M = Rh, Ir; tpt = 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine) , P. Govindaswamy, G. Süss-Fink, B. Therrien , Inorg. Chem. Commun. 2007, 10, 1489-1492.

110-Tetra- and hexanuclear cage molecules based on diruthenium tetracarbonyl sawhorse units: Synthesis and molecular structure of [{Ru2(CO)4(PPh3)2}2(O2CCH2CO2)2] and [{Ru2(CO)4(PMe3)2}3(O2CC6H4CO2)3] , M. Auzias, B. Therrien, G. Süss-Fink, Inorg. Chem. Commun., 2007, 10, 1420-1424.

109-An imine ligand avoiding imine-enamine equilibrium and cyclopalladation: Synthesis and coordination of Me3C6H2CH2N=CHtBu, L. Chahen, B. Therrien, G. Süss-Fink, Inorg. Chem. Commun. 2007 , 10 , 1375-1377 .

108- Hexacationic metalloprisms of the type /// [Cp*6M6(μ3-tpt-κN)2(μ-C2O4-κO)3] 6+ (M = Rh, Ir, tpt = 2,4,6-Tri(pyridin-4-yl)-1,3,5-triazine ) with double helical chirality , P. Govindaswamy, D. Linder, J. Lacour, G. Süss-Fink, B. Therrien , Dalton Trans. 2007, 4457-4463.

107-Di-μ-chloro-bis [(η6-toluene)chlororuthenium(II)], J. Mattsson , B. Therrien, Acta Cryst. 2007, E63, m2757.

106-Square-planar diacetato palladium complexes with trans-configurated secondary amine ligands avoiding ortho-metallation: Ligand synthesis, coordination, molecular structure and catalytic potential for Suzuki cross-coupling reactions, L. Chahen, B. Therrien, G. Süss-Fink, Eur. J. Inorg. Chem. 2007 , 5045-5051.

105-(+/-)- Di-μ-chloro-dichloro /// [N,N'-{3,3'-methylenebis(2,4,6-trimethyl-3,1-phenylene)}-bis(methylene)bis(2-methylpropan-2-amino)] dipalladium(II), L. Chahen, B. Therrien, G. Süss-Fink, Acta Cryst. 2007, E63, m2687.

104-Remarkable anticancer activity of triruthenium-arene clusters compared to tetraruthenium-arene clusters , B. Therrien, W. H. Ang, F. Chérioux, L. Vieille-Petit, L. Juillerat-Jeanneret, G. Süss-Fink, P. J. Dyson, J. Clust. Sci. 2007 , 18, 741-752.

103-1,1'-Ferrocene dicarboxylic acid pyridine-4-yl ester: A new bidentate ligand in arene ruthenium chemistry , M. Auzias, B. Therrien, G. Süss-Fink, Inorg. Chem. Commun., 2007, 10, 1239-1243.

102- Dinuclear ruthenium complexes containing chelating 6,7-dimethyl-2,3-di(2-pyridyl)quinoxaline ligand: Synthesis, molecular structure and catalytic properties, B. Therrien , G. Süss-Fink, P. Govindaswamy, C. Saïd-Mohamed, Polyhedron 2007, 26, ///4065-4072.

101- Reactivity studies of cyclopentadienyl ruthenium(II), osmium(II) and pentamethylcyclopentadienyl iridium(III) complexes towards 2-(2'-pyridyl)imidazoles , K. Pachhunga, B. Therrien, K. A. Kreisel, G. P. A. Yap, K. Mohan Rao, Polyhedron 2007, 26, 3638-3844.

100-Mono and dinuclear rhodium, iridium and ruthenium complexes containing chelating 2,2'-bipyrimidine ligands: Synthesis, molecular structure, electrochemistry and catalytic properties , P. Govindaswamy, J. Canivet, G. Süss-Fink, B. Therrien , P. těpnička, J. Ludvík, J. Organomet. Chem. 2007, 692, 3664-3675 .

99-μ-Oxalato-bis [(η5-pentamethylcyclopentadienyl)(trifluoromethanesulfonato)rhodium(III)], P. Govindaswamy, G. Süss-Fink, B. Therrien, Acta Cryst. 2007, E63, m2046 .

98- Dinuclear arene-ruthenium complexes containing a chiral phosphido bridge , M. Tschan, G. Süss-Fink, F. Chérioux, B. Therrien , Eur. J. Inorg. Chem. 2007, 3091-3100.

97- Di-μ-diphenylphosphido-bis [{(mesithylmethyl)(diphenyl)phosphine}chloropalladium(II)], L. Chahen, B. Therrien, G. Süss-Fink, Acta Cryst. 2007, E63, m1989.

96-Chloro(η6-1,2,4,5-C6H2Me4)(η2-6,7-dimethyl-2,3-di(pyridin-2-yl)quinoxaline-κN,N') ruthenium(II) hexafluorophosphate acetonitrile solvate , B. Therrien , G. Süss-Fink, Acta Cryst. 2007, E63, m1627 .

95-Di-μ-chloro-bis [(η5-pentamethylcyclopentadienyl)chlororhodium(III)] trichloroform solvate, P. Govindaswamy, G. Süss-Fink, B. Therrien, Acta Cryst. 2007, E63, m931-m932 .

94-Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry ,P. Govindaswamy, G. Süss-Fink, B. Therrien , P. tĕpnička, J. Ludvík, J. Organomet. Chem. 2007, 692, 1661-1671.

93-Synthesis, molecular structure and catalytic potential of the tetrairon complex [Fe4(N3O2-L)4(μ-O)2 ] 4+ (L = 1-carboxymethyl-4,7-dimethyl-1,4,7-triazacyclononane) ,V. B. Romakh, B. Therrien, G. Süss-Fink, G. B. Shul'pin, Inorg. Chem. 2007 , 46, 3166-3175.

92- Dinuclear manganese complexes containing chiral 1,4,7-triazacyclononane-derived ligands and their catalytic potential for the oxidation of olefins, alkanes and alcohols , V. B. Romakh, B. Therrien, G. Süss-Fink, G. B. Shul'pin, Inorg. Chem. 2007 , 46, 1315-1331.

91- Synthesis, molecular structure and electrochemistry of cationic diruthenium complexes of the type [(N∩N)2Ru2(CO)2(µ-OOCFc)] + containing a ferrocene carboxylato bridge and two chelating aromatic diimine ligands , M. Auzias, B. Therrien , G. Süss-Fink, P. tĕpnička, J. Ludvík, J. Organomet. Chem. 2007, 692, 755-760.

90-Self-assembled chloro-bridged arene ruthenium metallo-prisms: Synthesis and molecular structure of cationic complexes of the type [Ru6(η6-arene)6(μ3-tpt)2Cl6] 6+ , P. Govindaswamy, G. Süss-Fink, B. Therrien , Organometallics 2007, 26, 915-924.

89-A surprising reaction of trimethylphosphine with the unsaturated diruthenium complex [(C6Me6)2Ru2(H)3] + : Synthesis and molecular structure of the substitution product [(C6Me6)Ru2(PMe3)3(H)3]+ and the intermediate [(C6Me6)2Ru2(PMe3)2(H)(H)2]+ , M. Tschan, F. Chérioux, B. Therrien , G. Süss-Fink, Eur. J. Inorg. Chem. 2007, 509-513.

88-Ruthenium nanoparticles intercalated in hectorite: A reusable hydrogenation catalyst for benzene and toluene, G. Süss-Fink, B. Mollwitz, B. Therrien, M. Dadras, G. Laurenczy, A. Meister, G. Meister, J. Clust. Sci., 2007, 18, 87-95.

87-Dinuclear arene ruthenium and osmium trihydrido complexes: Versatile water-soluble synthons in organometallic chemistry , G. Süss-Fink, B. Therrien , Organometallics 2007, 26, 766-774.

86-Highly selective hydrogenation of carbon-carbon multiple bonds catalyzed by the cation [(C6Me6)2Ru2(PPh2)H2] +. Molecular structure of [(C6Me6)2Ru2(PPh2)(CHCHPh)H] +, a possible intermediate in the case of phenylacetylene hydrogenation, M. Tschan, G. Süss-Fink, F. Chérioux, B. Therrien, Chemistry, Eur. J. 2007, 13, 292-299.

85-μ-(p-SC6H4OH)-μ-(PPh2)-μ-(H)-bis [(η6-hexamethylbenzene)ruthenium(II)] [BF4], M. J.-L. Tschan, F. Chérioux, B. Therrien , L. Karmazin-Brelot, G. Süss-Fink, Acta Cryst. 2006, E62, m2916-m2918.

84- Self-assembled arene ruthenium metallo-prisms with unexpected helical chirality , P. Govindaswamy, D. Linder, J. Lacour, G. Süss-Fink, B. Therrien , Chem. Commun. 2006, 4691-4693.

83- Dinuclear hexamethylbenzene ruthenium cations containing σ-π-ferrocenoethenyl ligands: Synthesis, structure, electrochemistry , M. J.-L. Tschan, B. Therrien, J. Ludvík, P. těpnička, G. Süss-Fink, J. Organomet. Chem. 2006, 691, 4304-4311.

82-New mono and dinuclear arene ruthenium chloro complexes containing ester substituents , B. Therrien , G. Süss-Fink, Inorg. Chim. Acta 2006, 359, 4350-4354.

81-Square-planar dichloro palladium complexes with trans-configurated phosphine ligands avoiding ortho-metallation: Ligand design, complex synthesis, molecular structure and catalytic potential for Suzuki cross-coupling reactions, L. Chahen, B. Therrien, G. Süss-Fink, J. Organomet. Chem. 2006 , 691, 4257-4264.

80-(Pentamethylcyclopentadienyl){(R,R)-1-N-(p-toluenesulfonylamido)-2-aminocyclohexane-N,N'}chloroiridium(III) chloroform solvate, J. Canivet, B. Therrien, G. Süss-Fink, Acta Cryst. 2006, E62, m2435-m2436 .

79-Assembly state of catalytic modules as chiral switch in asymmetric Strecker amino acid synthesis, N. Kato, T. Mita, M. Kanai, B. Therrien, M. Kawano, M. Fujita,   K. Yamaguchi, H. Danjo, Y. Sei, A. Sato, S. Furusho, M. Shibasaki J. Am. Chem. Soc., 2006, 128, 6768-6769.

78- trans- Dichloro{[3,3'-oxybis(phenylene-methylene)] bis(diphenylphosphine)}palladium(II), L. Chahen, B. Therrien, G. Süss-Fink, Acta Cryst. 2006, E62, m1270-m1271.

77- Dinuclear iron, ruthenium and cobalt complexes containing 1,4-dimethyl-1,4,7-triazacyclononane ligands as well as carboxylato and oxo bridges , V. B. Romakh, B. Therrien, L. Karmazin-Brelot, G. Labat, H. Stoeckli-Evans, G. B. Shul'pin, G. Süss-Fink, Inorg. Chim. Acta 2006 , 359, 3297-3305.

76- 2-(Cyclohexa-1,4-dienyl)acetic acid , B. Therrien , G. Süss-Fink, Acta Cryst. 2006, E62, o1877-o1878.

75-Ru2(CO)4(OOCR)2(PPh3)2 sawhorse-type complexes containing μ22-carboxylato ligands derived from biologically active acids , M. Auzias, B. Therrien , G. Süss-Fink, Inorg. Chim. Acta 2006, 359, 3412-3416.

74-μ-Chloro-μ-(diphenylphosphido)-μ-hydrido-bis[(η6-hexamethylbenzene)ruthenium(II)][BF4] M. J.-L. Tschan, B. Therrien , G. Süss-Fink, Acta Cryst. 2006, E62, m954-m956.

73- Dinuclear manganese complexes containing 1,4-dimethyl-1,4,7-triazacyclononane ligands as well as carboxylato and oxo bridges ,V. B. Romakh, B. Therrien, L. Karmazin-Brelot, G. Labat, H. Stoeckli-Evans, G. B. Shul'pin, G. Süss-Fink, Inorg. Chim. Acta 2006 , 359, 1619-1626.

72- Calix[3]amides-bowl-shaped cyclic trimers toward building block for molecular recognition: self-complementary dimeric structure in the crystal , F. Imabeppu, K. Katagiri, H. Masu, T. Kato, M. Tominaga, B. Therrien , H. Takayanagi, E. Kaji, K. Yamaguchi, H. Kagechika, I. Azumaya, Tetrahedron Lett., 2006, 47, 413-416.

71- Dinuclear ruthenium sawhorse-type complexes containing ferrocenyl substituents in endo/endo, endo/exo and exo/exo orientations , M. Auzias, B. Therrien , G. Labat, H. Stoeckli-Evans, G. Süss-Fink, Inorg. Chim. Acta 2006, 359, 1012-1017.

70-Synthesis and molecular structures of mixed-metal cluster cations containing arene and hydrido ligands, V. Romakh, B. Therrien, G. Süss-Fink, Inorg. Chim. Acta 2006 , 359, 907-911.

69- Synthesis and characterization of tetrahedral Ru3O clusters with intrinsic framework chirality: A chiral probe of the intact cluster catalysis concept , L. Vieille-Petit, G. Süss-Fink, B. Therrien, T. R. Ward, H. Stoeckli-Evans, G. Labat, L. Karmazin-Brelot, A. Neels, T. Bürgi, R.G. Finke, C. M. Hagen, Organometallics 2005 , 24, 6104-6119.

68-[Ru2(CO)4(HNOCtBu)2(PPh3)2], M. Auzias, B. Therrien , G. Süss-Fink, Acta Cryst. 2005, E61, m2426-m2427.

(η 6 -C6H5CH2CH2OH)bis(η 6 - C6Me6 )tri-μ-hydrido-μ 3 -oxo-triruthenium tetrafluoroborate , L. Vieille-Petit, B. Therrien, G. Süss-Fink Private Commun . 2005 , CCDC 287293.

67-Syntheses of hexakis(4-functionalised-phenyl)benzene compounds directed to host molecules for guest-inclusion networks, K. Kobayashi, N. Kobayashi, M. Ikuta, B. Therrien , S. Sakamoto, K. Yamaguchi, J. Org. Chem. 2005 , 70, 749-752.

66-Synthesis, structure and properties of star-like dinuclear organometallic complexes functionalized with thiophenes , F. Chérioux, B. Therrien , S. Sadki, C. Comminges, G. Süss-Fink, J. Organomet. Chem. 2005, 690, 2365-2371.

65-Square-planar carbonylchlororhodium(I) complexes containing trans-spanning diphosphine ligands as catalysts for the carbonylation of methanol, S. Burger, B. Therrien, G. Süss-Fink, Helv. Chim. Acta 2005 , 88, 478-486.

64- Sulfur-containing trinuclear arene ruthenium clusters , M. Tschan, F. Chérioux, B. Therrien , G. Süss-Fink, J. Mol. Struct. 2005, 743, 177-181.

63-X-ray crystallographic study of two dinuclear triply-bridged  p-cymene osmium complexes , B. Therrien , L. Vieille-Petit, G. Süss-Fink, J. Mol. Struct. 2005, 738, 163-165.

62-[RuCl2(C6H6)]2 chloroform disolvate, J. Canivet, B. Therrien , G. Süss-Fink, Acta Cryst. 2005, E61, m1090-m1091.

61- X-ray crystallographic study of the hydrogen-bonded systems formed between di- and tricarboxylic acids and the trinuclear cluster cation [H3Ru3(C6H6)(C6Me6)2(O)] + , B. Therrien , L. Vieille-Petit, G. Süss-Fink, J. Mol. Struct. 2005 , 749, 183-186.

60-ent-Halimane diterpenes and guaiane sesquiterpene from Cladogynos Orientalis , M. Kanlayavattanakul, N. Ruangrungsi, T. Watanabe, M. Kawahata, B. Therrien , K. Yamaguchi, T. Ishikawa, J. Nat. Prod. 2005 , 68, 7-10.

59-Sequence-selective recognition of peptides within a self-assembled coordination cage , S. Tashiro, M. Tominaga, M. Kawano, B. Therrien, T. Ozeki, M. Fujita , J. Am. Chem. Soc. 2005, 127, 4546-4547.

58-Coordination architecture from a Pd(II)-cornered square complex , M. Fujita, M. Tominaga, A. Hori, B. Therrien , Acc. Chem. Res. 2005, 38, 369-378.

57-[RuCl2(1,2,4-C6H3Me3)]2 dichloromethane solvate (3/2) , B. Therrien , G. Süss-Fink, Acta Cryst. 2004, E60, m1766-m1768.

56-μ-Chloro- μ-hydrido-bis[chloro(η 6- p-cymene)ruthenium(II)](Ru-Ru): a second polymorph , B. Therrien , S. Frein, G. Süss-Fink, Acta Cryst. 2004 , E60, m1666-m1668.

55- Hydrogen-bonded systems between monocarboxylic acids and the trinuclear cluster cation [H3Ru3(C6H6)(C6Me6)2(O)] + : CSI-MS and X-ray crystallographic studies B. Therrien , L. Vieille-Petit, G. Süss-Fink, Y. Sei, K. Yamaguchi, J. Organomet. Chem. 2004 , 689, 2820-2826.

54-(η -C6H4MeR)bis( η 6 - durene )tri-μ-hydrido-μ 3 -oxo-triruthenium tetrafluoroborate, L. Vieille-Petit, B. Therrien, A.Buryak, K. Severin, G. Süss-Fink Acta Cryst . 2004 , E60, m1909-m1911.

53-Host-guest properties of the trinuclear ruthenium cluster cation [H3Ru3(C6H6)(C6Me6)2(O)] + B. Therrien , L. Vieille-Petit, G. Süss-Fink, Inorg. Chim. Acta 2004 , 357, 3289-3294.

52-[PtCl2(trans-1,2‑bis‑N‑[2'‑(diphenylphosphino)benzoyl]diaminocyclohexane)] · 3 CHCl3 , S. Burger, B. Therrien, G. Süss-Fink, Acta Cryst. 2004 , E60, m1163-m1165.

51- Subsequent hydride substitution in (arene)trihydridodiruthenium complexes: Synthesis and structure of thiolato-bridged diruthenium cations , M. Tschan, F. Chérioux, B. Therrien , G. Süss-Fink, Eur. J. Inorg. Chem. 2004, 2405-2411.

50-Dichloro( h 6 -p-cymene){ η 1- (2,4,6-tri-tbutylphenyl)phosphine}osmium B. Therrien , A.K. Burrell, Acta Cryst. 2004, E60, m863-m864.

49-2,3,4,7-Tetrahydro-1H-inden-2-ol: Synthesis, molecular structure and coordination chemistry, L. Vieille-Petit, B. Therrien, G. Süss-Fink, Polyhedron 2004 , 23, 687-691.

48- An iterative strategy for synthesis of oligothiophenes by catalytic cross-coupling reactions , T. Pinault, F. Chérioux, B. Therrien , G. Süss-Fink, Heteroatom Chem. 2004, 15, 121-126.

47-Synthesis of new Ru(II) thiolato complexes of the type [Ru2( η 6-arene)2(μ-p-SC6H4Br)3] + , F. Chérioux, B. Therrien , G. Süss-Fink, Inorg. Chim. Acta 2004, 357, 834-838.

46-Elimination of sulfur from aromatic heterocycles by a water-soluble arene ruthenium cluster: Synthesis and molecular structure of [H2S2Ru4(C6H6)4]Cl2 , F. Chérioux, B. Therrien , G. Süss-Fink, Chem. Commun. 2004, 204-205.

45-Supramolecular cluster catalysis: Facts and Problems, G. Süss-Fink, B. Therrien, L. Vieille-Petit, M. Tschan, V.B. Romakh, T.R. Ward, M. Dadras, G. Laurenczy, J. Organomet. Chem . 2004 , 689, 1362-1369.

44-Tetrakis-{[( η 6-1-isopropyl-4-methyl-benzene)ruthenium(II)] molybdate(VI)} , B. Therrien , L. Plasseraud, G. Süss-Fink, Inorg. Synth. 2004, 34, 200-203.

43-Asymmetric trihydrido-bridged arene ruthenium complexes, L. Vieille-Petit, B. Therrien, G. Süss-Fink, Inorg. Chem. Comm. 2004 , 7, 232-234.

42-Synthesis and molecular structures of the trinuclear ruthenium cluster cation [H3Ru3(C6H4(CH2)2OCOPh)(C6Me6)2(O)] + and [H3Ru3(C6H4(CH2)2OCO(CH2)3Ph)(C6Me6)2(O)] +, L. Vieille-Petit, B. Therrien, G. Süss-Fink, Inorg. Chim. Acta 2004 , 357, 3437-3442.

41- New dinuclear arene ruthenium complexes with P,S- or P,O- chelating ligands, S. Burger, B. Therrien, G. Süss-Fink, Inorg. Chim. Acta 2004 , 357, 1213-1218.

40-Ruthenium(II) complexes with Fc-modified arene ligands: Synthesis and electrochemistry B. Therrien , L. Vieille-Petit, J. Jeanneret-Gris, P. tĕpnička, G. Süss-Fink, J. Organomet. Chem. 2004 , 689, 2456-2463.

39-Mono and oligonuclear vanadium complexes as catalysts for alkane oxidation: Synthesis, molecular structures, and catalytic potential, G. Süss-Fink, L. Gonzalez Cuervo, B. Therrien, H. Stoeckli-Evans, G. B. Shul'pin, Inorg. Chim. Acta 2004, 357, 475-484.

38-New arene ruthenium complexes with planar chirality B. Therrien , G. Süss-Fink, Inorg. Chim. Acta 2004 , 357, 219-224.

37-2-(Diphenylphosphinoyl)benzoic acid chloroform solvate, S. Burger, B. Therrien, G. Süss-Fink, Acta Cryst . 2003 , E59, o1336-o1338.

36-[RhCl3{2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine}] · monohydrate B. Therrien, G. Süss-Fink, Acta Cryst . 2003 , E59, m806-m808

35-(η 6 -Benzene)bis( η 6 - p -cymene)tri-μ-hydrido-μ 3 -oxo-triruthenium hexafluorophosphate, L. Vieille-Petit, B. Therrien, G. Süss-Fink, Acta Cryst . 2003 , E59, m669-670.

34- Chiral arene ruthenium complexes: Synthesis and molecular structure of the enantiopure cluster cation (R)-[H3Ru3{C6H5(CH(CH3)CH2OH)}(C6Me6)2(O)] + , L. Vieille-Petit, B. Therrien, G. Süss-Fink, Eur. J. Inorg. Chem. 2003 , 3707-3711.

33-1,2‑Bis‑N‑[2'‑(diphenylphosphino)benzoyl]diaminobenzene, a new chelating ligand with versatile coordination properties, S. Burger, B. Therrien, G. Süss-Fink, Eur. J. Inorg. Chem. 2003 , 3099-3103.

32-Synthesis and molecular structures of the trinuclear ruthenium cluster cations [H3Ru3(C6H6)(C6H2Me4)2(O)]+ and [H3Ru3{C6H5(CH2)2OH}(C6H2Me4)2(O)] +, L. Vieille-Petit, B. Therrien, G. Süss-Fink, Inorg. Chim. Acta 2003 , 355, 394-398.

31-Supramolecular cluster catalysis: A case study of benzene hydrogenation , B. Therrien , L. Vieille-Petit, M. Tschan, V.B. Romakh, G. Süss-Fink, Chimia 2003 , 57, 593-596.

30-Synthesis of a trinuclear cation [H3Ru3(Fc-arene)(C6Me6)2(O)]+ containing a ferrocenyl group tethered to an arene ligand, L. Vieille-Petit, S. Unternährer, B. Therrien, G. Süss-Fink, Inorg. Chim. Acta 2003 , 355, 335-339.

29-Decacarbonyltetra- [mu] -hydrido-bis(tricyclohexylphosphine)- tetrahedro -tetraruthenium , E. Lozano Diz, B. Therrien, G. Süss-Fink, Acta Cryst. 2003, E59, m431-m433

28-Di- m -iodo-bis[dicarbonylrhodium(I)] , S. Burger, B. Therrien, G. Süss-Fink, Acta Cryst . 2003 , E59, i53-i54

27-Isolation and single-crystal X-ray structure analysis of the catalyst-substrate host-guest complexes [C6H6 ÌH3Ru3{C6H5(CH2)nOH}(C6Me6)2(O)] + (n = 2,3) , L. Vieille-Petit, B. Therrien, G. Süss-Fink, T.R. Ward, J. Organomet. Chem . 2003 , 684, 117-123.

26-First star-like oligophenylene molecules containing a dinuclear organometallic core , F. Chérioux, B. Therrien , G. Süss-Fink, Eur. J. Inorg. Chem. 2003, 1043-1047

25-Fe, Co, Ni & Ru complexes of 2,6-bis(3,4-dihydro-2 H-pyrrol-5-yl)Py, a pybox analogue, A. Cabort, A. Michel, B. Therrien, H. Stoeckli-Evans, K. Bernauer, G. Süss-Fink, A. F. Williams, G. Stupka, Inorg. Chim. Acta . 2003 , 350, 193-200

24-Copper(II) azido complexes containing trinitrogen ligands: [Cu( η 3-L)(N3)]2[Cu2Cl2(N3)4], a tridimensional network of cationic and anionic copper complexes, A. Cabort, B. Therrien , K. Bernauer, G. Süss-Fink, Inorg. Chim. Acta . 2003 , 349, 78-84

23-[RuCl2( η 6 -indane)]2 dichloroform solvate, L. Vieille-Petit, B. Therrien, G. Süss-Fink, Acta Cryst . 2002 , E58, m656-m657

22-[RhCl3{2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine}] · 2 C6H6 , A. Cabort, B. Therrien , K. Bernauer, G. Süss-Fink, Acta Cryst . 2002 , E58, m564-m565

21-[RuCl{2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine}(PPh3)2]BF4 · CH2Cl2 , A. Cabort, B. Therrien , K. Bernauer, G. Süss-Fink, Acta Cryst . 2002 , E58, m557-m558

20-New benzotriazole derivatives as multifunctional ligands, C.M. Thomas, B. Therrien, A. Neels, H. Stoeckli-Evans, G. Süss-Fink J. Organomet. Chem. 2002, 658, 251-258

19-Ligand dehydrogenation in ruthenium trinitrogen complexes: synthesis, structure and chirality of the cations [Ru(LH4)(L)] 2+ [LH4=2,6-bis(pyrrolidin-2-yl)pyridine], A. Cabort, B. Therrien , H. Stoeckli-Evans, K. Bernauer, G. Süss-Fink, Inorg. Chem. Comm. 2002, 5, 787-790

18- Dendritic systems based on Ru or Rh units with generation of peripheral catalytic sites, F. Chérioux, C. M. Thomas, B. Therrien , G. Süss-Fink, Chem. Eur. J. 2002, 8, 4377-4382

17- New diphosphine ligands containing ethylene glycol and amino alcohol spacers for the rhodium-catalysed carbonylation of methanol, C.M. Thomas, R. Mafua, B. Therrien , E. Rusanov, H. Stoeckli-Evans, G. Süss-Fink, Chem. Eur. J. 2002, 8, 3343-3352

16- A new heteronuclear trirutheniumcobalt cluster containing a bulky phosphine ligand , E. Lozano Diz, B. Therrien, G. Süss-Fink, Acta Cryst. 2002, E58, m451-m453

15-Dibromodicarbonylbis(triphenylphosphine)ruthenium(II) dichloromethane solvate , E. Lozano Diz, B. Therrien, A. Neels, G. Süss-Fink, Acta Cryst. 2002, E58, m404-m405

14-Tetrabuthylammonium bis(malonato)oxovanadate(IV) , B. Therrien , S. Stanislas, H. Stoeckli-Evans, G.B. Shul'pin, G. Süss-Fink, Acta Cryst. 2002, E58 , m217-m219

13-A cluster containing a pyrazole ligand: [Ru 3 ( [mu] -H)( [mu] -N 2 C 3 H 3 )(CO) 10 ] , E. Lozano Diz, A. Neels, B. Therrien, H. Stoeckli-Evans, G. Süss-Fink, Acta Cryst. 2002, E58 , m110-m112

12- N,N'-Dicyclohexyl-N-(2-pyrazinoyl)urea , F. Chérioux, B. Therrien, H. Stoeckli-Evans, G. Süss-Fink, Acta Cryst. 2002, E58 , o27-o29

11-[5,15-Bis(4-pyridyl)-2,8,12,18-tetra-n-butyl-3,7,13,17-tetramethylporphyrinato]zinc(II), K.Y. Wild, B. Therrien, P.G. Plieger, D.L. Officer, A.K. Burrell, Acta Cryst. 2001, E57, m478-m479

10-5-Bromo-2-hydroxybenzene-1,3-dicarbaldehyde, S. Duclos, B. Therrien, T.R. Ward, Acta Cryst. 2001, E57, o884-o885

9-Dichloro( h 5 -pentamethylcyclopentadienyl)(pyridine-N)rhodium , B. Therrien , A.K. Burrell, Acta Cryst. 2001, E57, m259-m260

8-Chloro(1-{3-[2-(diphenylphosphanyl- k P )ethyl]- h 6 -benzyl}-3,5-dimethyl-1H-pyrazole- k N 2 )ruthenium(II) trifluoromethanesulfonate B. Therrien , T.R. Ward, Acta Cryst. 2000, C56, e561

7- Atropisomeric transition state analogs, O. Ritzeler, S. Parel, B. Therrien, N. Bensel, J.-L. Reymond, K. Schenk, Eur. J. Org. Chem. 2000, 1365-1372.

6-Synthesis of a configurationally stable three legged piano stool complex B. Therrien , T.R. Ward, Angewandte Chemie Int. Ed. 1999, 38, 405-408.

5-Chiral configurationally stable three legged piano stool complexes B. Therrien , A. König, T.R. Ward, Organometallics 1999, 18, 1565-1568.

4-1,1'-Dimethyl-2, 2'-biimidazole B. Therrien , A.L. Beauchamp, Acta Cryst. 1999, C55, IUC9900054

Synthesis of a configurationally stable, three legged piano stool complex B. Therrien , Inauguraldissertation, PhD Thesis, Berne 1998

3-Coordination properties of Kläui's tripodal oxygen donor towards zirconium(IV), S. Duclos, B. Therrien, T.R. Ward, K. Schenk, Organometallics 1998, 17, 2490-2494

2-Synthesis and reactivity of tethered η 1 :η 6-(phosphinoarene)ruthenium dichlorides B. Therrien , T.R. Ward, M. Pilkington, C. Hoffmann, F. Gilardoni, J. Weber, Organometallics 1998, 17, 330-337

1-Structures of NbCl6 salts of the 1-Me-Im/1-Me-imidazolium and 2-Me-imidazolium cations B. Therrien , A.L. Beauchamp, Acta Cryst. 1993, C49, 1303-07

Réactions du niobium(V) avec l'imidazole et certains de ses dérivés méthylés B. Therrien , Mémoire de Maîtrise, Université de Montréal, Montréal 1993